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Structure[ edit ] The anion is the conjugate base of nitric acidconsisting of one central nitrogen atom surrounded by three identically bonded oxygen atoms in a trigonal planar arrangement. This arrangement is commonly used as an example of resonance.
Like the isoelectronic carbonate ion, the nitrate ion can be represented by resonance structures: Properties and diet[ edit ] The nitrate ion with the partial charges shown Almost all inorganic nitrate salts are soluble in water at standard temperature and pressure.
A common example of an inorganic nitrate salt is potassium nitrate saltpeter. A rich source of inorganic nitrate in the human body comes from diets rich in leafy green foods, such as spinach and arugula.
Dietary nitrate may be found in cured meatsvarious leafy vegetables, and drinking water; nitrite consumption is primarily determined by the amount of processed meats eaten, and the concentration of nitrates in these meats.
Nitrite and water are converted in the body to nitric oxidewhich could reduce hypertension.
Anti-hypertensive diets, such as the DASH diettypically contain high levels of nitrates, which are first reduced to nitrite in the saliva, as detected in saliva testingprior to forming nitric oxide.
Nitrites are produced by a number of species of nitrifying bacteriaand the nitrate compounds for gunpowder see this topic for more were historically produced, in the absence of mineral nitrate sources, by means of various fermentation processes using urine and dung.
Nitrates are found in fertilizers. Uses[ edit ] Table tennis balls are made from celluloid, an organic nitrate. Nitrates are mainly produced for use as fertilizers in agriculture because of their high solubility and biodegradability.
The main nitrate fertilizers are ammonium, sodium, potassium, and calcium salts. Several million kilograms are produced annually for this purpose. Sodium nitrate is used to remove air bubbles from molten glass and some ceramics.
Mixtures of the molten salt are used to harden some metals. Explosives and table tennis balls are made from celluloid. In the early 20th century, most motion picture film was made of nitrocellulosebut the intense flammability of the film led to it being replaced with "safety film" by the midth-century.
Although nitrites are the nitrogen compound chiefly used in meat curing, nitrates are used in certain specialty curing processes where a long release of nitrite from parent nitrate stores is needed. The use of nitrates in food preservation is controversial.
This is due to the potential for the formation of nitrosamines when nitrates are present in high concentrations and the product is cooked at high temperatures.
An alternative method for nitrate and nitrite analysis is enzymatic reduction using nitrate reductase   which has recently been proposed by the US Environmental Protection Agency as an alternate test procedure for determining nitrate.
Such electrodes function analogously to the pH selective electrode. This response is partially described by the Nernst equation. Poisoning[ edit ] Nitrate poisoning can occur through enterohepatic metabolism of nitrate due to nitrite being an intermediate.
Although nitrite converts to ammoniaif there is more nitrite than can be converted, the animal slowly suffers from a lack of oxygen.
Methemoglobinemia in infants is known as blue baby syndrome. Although nitrates in drinking water once were thought to be a contributing factor, there now are significant scientific doubts as to whether there is a causal link. Nitrates, if a factor in a specific case, would most often be ingested by infants in high nitrate drinking water, however, nitrate exposure also may occur if eating, for instance, vegetables containing high levels of nitrate.
Lettuce may contain elevated nitrate under growth conditions such as reduced sunlight, undersupply of the essential micronutrients molybdenum Moand iron Feor high concentrations of nitrate due to reduced assimilation of nitrate in the plant.
High levels of nitrate fertilization also contribute to elevated levels of nitrate in the harvested plant. The methemoglobin reductase enzyme may be under-produced or absent in certain people who have an inherited mutation. Those with insufficient stomach acid,  including some vegetarians and vegans, may also be at risk.Bioaccumulation of heavy metals in some tissues of fish in the Red Sea, Egypt.
This study reports the concentration levels of selected essential metals; Ca, Mg, Na, K, Fe and Zn in the drinking water collected from different areas of Islamabad.
The levels of these metals present in the drinking ground water were compared with standards reported worldwide. One interesting study compared the levels of toxic metals (arsenic, cadmium, and lead) in mothers with insulin-dependent diabetes and their infants, to mothers without diabetes and their rutadeltambor.com researchers found that levels of all these metals were significantly higher in the women with diabetes and their infants than in the women without .
Based on the results of this study, it can be concluded that Cannabis sativa L. contains higher levels of essential metals Ca, Zn and Cu. But highly toxic metals like Pb . Chelation Therapy. How do you safely get rid of heavy metals and toxins in the body?
Is fish safe to consume? What is the best chelating agent, and how can one minimize chelation therapy side effects? Urine Toxic Metals. Urine Elements are traditionally used to evaluate exposure to potentially toxic elements and wasting of nutrient elements. Additionally, the comparison of urine element concentrations before and after administration of a chelator can be used to estimate net retention of potentially toxic elements.